dorsal/arxiv
View SchemaNew examples of metalloaromatic Al-clusters: (Al4M4)Fe(CO)3 (M=Li, Na and K) and (Al4M4)2Ni: Rationalization for possible synthesis
| Authors | Ayan Datta, Swapan K. Pati |
|---|---|
| Categories | |
| ArXiv ID | physics/0509079 |
| URL | https://arxiv.org/abs/physics/0509079 |
Abstract
Ab-initio calculations reveal that all-metal antiaromatic molecules like Al4M4 (M=Li, Na and K) can be stabilized in half-sandwich complex: (Al4M4)Fe(CO)3 and full-sandwich complexes of the type: (Al4M4)2Ni. The formation of the full-sandwich complex [(Al4M4)2Ni] from its organometallic precursor depends on the stability of the organic-inorganic hybrid (C4H4) Ni (Al4Li4).
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"date_created": "2026-03-02T18:01:00.709000Z",
"date_modified": "2026-03-02T18:01:00.709000Z",
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"abstract": "Ab-initio calculations reveal that all-metal antiaromatic molecules like\nAl4M4 (M=Li, Na and K) can be stabilized in half-sandwich complex:\n(Al4M4)Fe(CO)3 and full-sandwich complexes of the type: (Al4M4)2Ni. The\nformation of the full-sandwich complex [(Al4M4)2Ni] from its organometallic\nprecursor depends on the stability of the organic-inorganic hybrid (C4H4) Ni\n(Al4Li4).",
"arxiv_id": "physics/0509079",
"authors": [
"Ayan Datta",
"Swapan K. Pati"
],
"categories": [
"physics.chem-ph",
"physics.atm-clus"
],
"title": "New examples of metalloaromatic Al-clusters: (Al4M4)Fe(CO)3 (M=Li, Na and K) and (Al4M4)2Ni: Rationalization for possible synthesis",
"url": "https://arxiv.org/abs/physics/0509079"
},
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