{
  "annotation_id": "e9f1c89a-1471-455e-9e33-92a26d212e34",
  "date_created": "2026-03-02T18:01:21.746000Z",
  "date_modified": "2026-03-02T18:01:21.746000Z",
  "file_hash": "1c4192fd3ff30fcfa10c9564dfc6c0647d16498cf231c633528dedb0eb0364de",
  "private": false,
  "record": {
    "abstract": "A theory of vibrational energy relaxation based on a semiclassical treatment\nof the quantum master equation is presented. Using new results on the\nsemiclassical expansion of dipole matrix elements, we show that in the\nclassical limit the master equation reduces to the Zwanzig energy diffusion\nequation. The leading quantum corrections are determined and discussed for the\nharmonic and Morse potentials.",
    "arxiv_id": "physics/9711028",
    "authors": [
      "Robert Karrlein",
      "Hermann Grabert"
    ],
    "categories": [
      "physics.chem-ph"
    ],
    "doi": "10.1063/1.475906",
    "title": "Semiclassical theory of vibrational energy relaxation",
    "url": "https://arxiv.org/abs/physics/9711028"
  },
  "schema_id": "dorsal/arxiv",
  "source": {
    "execution_id": "dc4a4b71-7012-4f74-9808-5ea769efce92",
    "id": "arXiv Dataset IDs",
    "type": "Model",
    "variant": "snapshot-2026-03-01",
    "version": "0.1.0"
  },
  "user_id": 1000002
}