{
  "annotation_id": "dd4a1805-2d70-4d9c-ae92-267a6d47a078",
  "date_created": "2026-03-02T18:00:59.879000Z",
  "date_modified": "2026-03-02T18:00:59.879000Z",
  "file_hash": "3d243a5564a9f5cf0702477dda8f7ba160e9a3a720b1bafc53209ccb7b78992c",
  "private": false,
  "record": {
    "abstract": "The article investigates a possible influence of the open chemical system\nreaction to the external impact on the system transition to a new equilibrium.\nPotential system response is taken as a combination of various powers of the\nreaction shift from thermodynamic equilibrium, leading to different equations\nfor the system Gibbs\u0027 free energy change. The investigation is focused on two\ntypes of the constraints which are put on the system - the \"soluble\",\ndisappearing when the stressed system achieves its new equilibrium, as it\nhappens in result of a temperature change, and \"insoluble\", still remaining\nactive in the new equilibrium. It was assumed that the \"soluble\" constraints\nactivate a wider selection of the reaction shift powers as the system Le\nChatelier response, providing for a smooth transition between two equilibrium\nstates. The \"insoluble\" constraints may suppress some higher powers in the\nresponse set, and transition may be accompanied by bifurcations.",
    "arxiv_id": "physics/0508185",
    "authors": [
      "B. Zilbergleyt"
    ],
    "categories": [
      "physics.chem-ph"
    ],
    "title": "Le Chatelier Response",
    "url": "https://arxiv.org/abs/physics/0508185"
  },
  "schema_id": "dorsal/arxiv",
  "source": {
    "execution_id": "75b4c061-5d7f-4cb3-9c1c-3ce3ad49fc3b",
    "id": "arXiv Dataset IDs",
    "type": "Model",
    "variant": "snapshot-2026-03-01",
    "version": "0.1.0"
  },
  "user_id": 1000002
}