dorsal/arxiv
View SchemaCeramic Methyltrioxorhenium
| Authors | Rudolf Herrmann, Klaus Troester, Georg Eickerling, Christian Helbig, Christoph Hauf, Robert Miller, Franz Mayr, Hans-Albrecht Krug von Nidda, Ernst-Wilhelm Scheidt, Wolfgang Scherer |
|---|---|
| Categories | |
| ArXiv ID | physics/0604046 |
| URL | https://arxiv.org/abs/physics/0604046 |
| DOI | 10.1103/PhysRevB.73.165113 |
| Journal | Physical Review B 73, 165113 (2006) |
Abstract
The metal oxide polymeric methyltrioxorhenium [(CH3)xReO3] is an unique epresentative of a layered inherent conducting organometallic polymer which adopts the structural motifs of classical perovskites in two dimensions (2D) in form of methyl-deficient, corner-sharing ReO5(CH3) octahedra. In order to improve the characteristics of polymeric methyltrioxorhenium with respect to its physical properties and potential usage as an inherentconducting polymer we tried to optimise the synthetic routes of polymeric modifications of 1 to obtain a sintered ceramic material, denoted ceramic MTO. Ceramic MTO formed in a solvent-free synthesis via auto-polymerisation and subsequent sintering processing displays clearly different mechanical and physical properties from polymeric MTO synthesised in aqueous solution. Ceramic MTO is shown to display activated Re-C and Re=O bonds relative to MTO. These electronic and structural characteristics of ceramic MTO are also reflected by a different chemical reactivity compared with its monomeric parent compound. First examples of the unprecedented reactivity of ceramic MTO in the field of amine oxidations are shown - results which warrant further exploitation.
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"abstract": "The metal oxide polymeric methyltrioxorhenium [(CH3)xReO3] is an unique\nepresentative of a layered inherent conducting organometallic polymer which\nadopts the structural motifs of classical perovskites in two dimensions (2D) in\nform of methyl-deficient, corner-sharing ReO5(CH3) octahedra. In order to\nimprove the characteristics of polymeric methyltrioxorhenium with respect to\nits physical properties and potential usage as an inherentconducting polymer we\ntried to optimise the synthetic routes of polymeric modifications of 1 to\nobtain a sintered ceramic material, denoted ceramic MTO. Ceramic MTO formed in\na solvent-free synthesis via auto-polymerisation and subsequent sintering\nprocessing displays clearly different mechanical and physical properties from\npolymeric MTO synthesised in aqueous solution. Ceramic MTO is shown to display\nactivated Re-C and Re=O bonds relative to MTO. These electronic and structural\ncharacteristics of ceramic MTO are also reflected by a different chemical\nreactivity compared with its monomeric parent compound. First examples of the\nunprecedented reactivity of ceramic MTO in the field of amine oxidations are\nshown - results which warrant further exploitation.",
"arxiv_id": "physics/0604046",
"authors": [
"Rudolf Herrmann",
"Klaus Troester",
"Georg Eickerling",
"Christian Helbig",
"Christoph Hauf",
"Robert Miller",
"Franz Mayr",
"Hans-Albrecht Krug von Nidda",
"Ernst-Wilhelm Scheidt",
"Wolfgang Scherer"
],
"categories": [
"physics.chem-ph"
],
"doi": "10.1103/PhysRevB.73.165113",
"journal_ref": "Physical Review B 73, 165113 (2006)",
"title": "Ceramic Methyltrioxorhenium",
"url": "https://arxiv.org/abs/physics/0604046"
},
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