dorsal/arxiv
View SchemaSpin-Lattice Relaxation in Metal-Organic Platinum(II) Complexes
| Authors | Herbert H. H. Homeier, Johann Strasser, Hartmut Yersin |
|---|---|
| Categories | |
| ArXiv ID | physics/9911076 |
| URL | https://arxiv.org/abs/physics/9911076 |
| DOI | 10.1016/S0009-2614(99)01298-1 |
| Journal | Chemical Physics Letters, Volume 316, Issue 3-4, 14 January 2000, Pages 280-284 |
Abstract
The dynamics of spin-lattice relaxation (slr) of metal-organic Pt(II) compounds is studied. Often, such systems are characterized by pronounced zero-field splittings (zfs) of the lowest-lying triplets. Previous expressions for the Orbach slr process do not allow to treat such splitting patterns properly. We discuss the behavior of a modified Orbach expression for a model system and present results of a fit of the temperature dependence of the spin-lattice relaxation rate of Pt(2-thpy)$_2$ based on the modified expression.
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"abstract": "The dynamics of spin-lattice relaxation (slr) of metal-organic Pt(II)\ncompounds is studied. Often, such systems are characterized by pronounced\nzero-field splittings (zfs) of the lowest-lying triplets. Previous expressions\nfor the Orbach slr process do not allow to treat such splitting patterns\nproperly. We discuss the behavior of a modified Orbach expression for a model\nsystem and present results of a fit of the temperature dependence of the\nspin-lattice relaxation rate of Pt(2-thpy)$_2$ based on the modified\nexpression.",
"arxiv_id": "physics/9911076",
"authors": [
"Herbert H. H. Homeier",
"Johann Strasser",
"Hartmut Yersin"
],
"categories": [
"physics.chem-ph"
],
"doi": "10.1016/S0009-2614(99)01298-1",
"journal_ref": "Chemical Physics Letters, Volume 316, Issue 3-4, 14 January 2000,\n Pages 280-284",
"title": "Spin-Lattice Relaxation in Metal-Organic Platinum(II) Complexes",
"url": "https://arxiv.org/abs/physics/9911076"
},
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