dorsal/arxiv
View SchemaElectron transfer theory revisit: Quantum solvation effect
| Authors | Ping Han, Rui-Xue Xu, Ping Cui, Yan Mo, Guozhong He, YiJing Yan |
|---|---|
| Categories | |
| ArXiv ID | physics/0606058 |
| URL | https://arxiv.org/abs/physics/0606058 |
Abstract
The effect of solvation on the electron transfer (ET) rate processes is investigated on the basis of the exact theory constructed in J. Phys. Chem. B Vol. 110, (2006); quant-ph/0604071. The nature of solvation is studied in a close relation with the mechanism of ET processes. The resulting Kramers' turnover and Marcus' inversion characteristics are analyzed accordingly. The classical picture of solvation is found to be invalid when the solvent longitudinal relaxation time is short compared with the inverse temperature.
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"abstract": "The effect of solvation on the electron transfer (ET) rate processes is\ninvestigated on the basis of the exact theory constructed in J. Phys. Chem. B\nVol. 110, (2006); quant-ph/0604071. The nature of solvation is studied in a\nclose relation with the mechanism of ET processes. The resulting Kramers\u0027\nturnover and Marcus\u0027 inversion characteristics are analyzed accordingly. The\nclassical picture of solvation is found to be invalid when the solvent\nlongitudinal relaxation time is short compared with the inverse temperature.",
"arxiv_id": "physics/0606058",
"authors": [
"Ping Han",
"Rui-Xue Xu",
"Ping Cui",
"Yan Mo",
"Guozhong He",
"YiJing Yan"
],
"categories": [
"physics.chem-ph"
],
"title": "Electron transfer theory revisit: Quantum solvation effect",
"url": "https://arxiv.org/abs/physics/0606058"
},
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