{
  "annotation_id": "c5dc5706-cc37-45ee-9c70-97d2bc066c49",
  "date_created": "2026-03-02T18:00:32.761000Z",
  "date_modified": "2026-03-02T18:00:32.761000Z",
  "file_hash": "0ebe07b5bd07b5760070f3062901fb07a9ee443a7a0d518dc9bd8cf16ca370c5",
  "private": false,
  "record": {
    "abstract": "The article presents new model of equilibrium in open chemical systems\nsuggesting a linear dependence of the reaction shift from equilibrium in\npresence of the external thermodynamic force. Basic equation of this model\ncontains traditional logarithmic term and a non-traditional parabolic term. At\nisolated equilibrium the non-traditional term equals to zero turning the whole\nequation to the traditional form of constant equation. This term coincides with\nthe excessive thermodynamic function revealing linear relationship between\nlogarithm of the thermodynamic activity coefficient and reaction extent at open\nequilibrium. Discovered relationship prompts us to use in many systems a\ncombination of the linearity coefficient and reaction shift from true\nequilibrium rather then activity coefficients. The coefficient of linearity can\nbe found by thermodynamic computer simulation while the shift is an independent\nvariable defining the open equilibrium state. Numerical data obtained by\nvarious simulation techniques proved premise of the method of chemical\ndynamics.",
    "arxiv_id": "physics/0004035",
    "authors": [
      "B. Zilbergleyt"
    ],
    "categories": [
      "physics.chem-ph"
    ],
    "title": "Thermodynamic Equilibrium in Open Chemical Systems",
    "url": "https://arxiv.org/abs/physics/0004035"
  },
  "schema_id": "dorsal/arxiv",
  "source": {
    "execution_id": "d6a71eb6-f91a-414b-b629-91b1806d4d90",
    "id": "arXiv Dataset IDs",
    "type": "Model",
    "variant": "snapshot-2026-03-01",
    "version": "0.1.0"
  },
  "user_id": 1000002
}