dorsal/arxiv
View SchemaProspects in Analytical Atomic Spectrometry
| Authors | A. A. Bol'shakov, A. A. Ganeev, V. M. Nemets |
|---|---|
| Categories | |
| ArXiv ID | physics/0607078 |
| URL | https://arxiv.org/abs/physics/0607078 |
| DOI | 10.1070/RC2006v075n04ABEH001174 |
| Journal | Russian Chemical Reviews, v. 75, pp. 289-302 (2006). [Translated from Uspekhi Khimii, v. 75, pp. 322-338 (2006)] |
Abstract
Tendencies in five main branches of atomic spectrometry (absorption, emission, mass, fluorescence and ionization spectrometry) are considered. The first three techniques are the most widespread and universal, with the best sensitivity attributed to atomic mass spectrometry. In the direct elemental analysis of solid samples, the leading roles are now conquered by laser-induced breakdown and laser ablation mass spectrometry, and the related techniques with transfer of the laser ablation products into inductively-coupled plasma. Advances in design of diode lasers and optical parametric oscillators promote developments in fluorescence and ionization spectrometry and also in absorption techniques where uses of optical cavities for increased effective absorption pathlength are expected to expand. Prospects for analytical instrumentation are seen in higher productivity, portability, miniaturization, incorporation of advanced software, automated sample preparation and transition to the multifunctional modular architecture. Steady progress and growth in applications of plasma- and laser-based methods are observed. An interest towards the absolute (standardless) analysis has revived, particularly in the emission spectrometry.
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"abstract": "Tendencies in five main branches of atomic spectrometry (absorption,\nemission, mass, fluorescence and ionization spectrometry) are considered. The\nfirst three techniques are the most widespread and universal, with the best\nsensitivity attributed to atomic mass spectrometry. In the direct elemental\nanalysis of solid samples, the leading roles are now conquered by laser-induced\nbreakdown and laser ablation mass spectrometry, and the related techniques with\ntransfer of the laser ablation products into inductively-coupled plasma.\nAdvances in design of diode lasers and optical parametric oscillators promote\ndevelopments in fluorescence and ionization spectrometry and also in absorption\ntechniques where uses of optical cavities for increased effective absorption\npathlength are expected to expand. Prospects for analytical instrumentation are\nseen in higher productivity, portability, miniaturization, incorporation of\nadvanced software, automated sample preparation and transition to the\nmultifunctional modular architecture. Steady progress and growth in\napplications of plasma- and laser-based methods are observed. An interest\ntowards the absolute (standardless) analysis has revived, particularly in the\nemission spectrometry.",
"arxiv_id": "physics/0607078",
"authors": [
"A. A. Bol\u0027shakov",
"A. A. Ganeev",
"V. M. Nemets"
],
"categories": [
"physics.ins-det"
],
"doi": "10.1070/RC2006v075n04ABEH001174",
"journal_ref": "Russian Chemical Reviews, v. 75, pp. 289-302 (2006). [Translated\n from Uspekhi Khimii, v. 75, pp. 322-338 (2006)]",
"title": "Prospects in Analytical Atomic Spectrometry",
"url": "https://arxiv.org/abs/physics/0607078"
},
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