dorsal/arxiv
View SchemaIncipient modulated phase in Sr$_{1-x}$Ca$_{x}$TiO$_3$
| Authors | Benoît Fauqué, Daniel A. Chaney, Philippe Bourges, Stéphane Raymond, Arno Hiess, Paul Steffens, Benoît Baptiste, Luigi Paolasini, Alexeï Bosak, Kamran Behnia, Yasuhide Tomioka |
|---|---|
| Categories | |
| ArXiv ID | 2601.10516vv1 |
| URL | https://arxiv.org/abs/2601.10516 |
| License | http://creativecommons.org/licenses/by/4.0/ |
Abstract
Nanometer-scale modulations can spontaneously emerge in complex materials when multiple degrees of freedom interact. Here we demonstrate that ferroelectric Sr$_{1-x}$Ca$_x$TiO$_3$ lies in close proximity to an incipient structurally modulated phase. Using inelastic neutron and X-ray scattering, we show that upon cooling, dipolar fluctuations strongly couple to and soften the $c_{44}$ transverse acoustic mode. We identify the wavevector at which this softening is maximal, thereby defining the characteristic length scale of the modulation. Calcium substitution enhances both the amplitude and the wavevector of the softening by strengthening the ferroelectric and antiferrodistortive instabilities. Our results demonstrate that nonlinear flexoelectric phonon coupling tends to stabilize a modulated state that cooperates with, rather than competes against, the other lattice instabilities in SrTiO$_3$.
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"abstract": "Nanometer-scale modulations can spontaneously emerge in complex materials when multiple degrees of freedom interact. Here we demonstrate that ferroelectric Sr$_{1-x}$Ca$_x$TiO$_3$ lies in close proximity to an incipient structurally modulated phase. Using inelastic neutron and X-ray scattering, we show that upon cooling, dipolar fluctuations strongly couple to and soften the $c_{44}$ transverse acoustic mode. We identify the wavevector at which this softening is maximal, thereby defining the characteristic length scale of the modulation. Calcium substitution enhances both the amplitude and the wavevector of the softening by strengthening the ferroelectric and antiferrodistortive instabilities. Our results demonstrate that nonlinear flexoelectric phonon coupling tends to stabilize a modulated state that cooperates with, rather than competes against, the other lattice instabilities in SrTiO$_3$.",
"arxiv_id": "2601.10516",
"authors": [
"Beno\u00eet Fauqu\u00e9",
"Daniel A. Chaney",
"Philippe Bourges",
"St\u00e9phane Raymond",
"Arno Hiess",
"Paul Steffens",
"Beno\u00eet Baptiste",
"Luigi Paolasini",
"Alexe\u00ef Bosak",
"Kamran Behnia",
"Yasuhide Tomioka"
],
"categories": [
"cond-mat.mtrl-sci",
"cond-mat.supr-con"
],
"license": "http://creativecommons.org/licenses/by/4.0/",
"title": "Incipient modulated phase in Sr$_{1-x}$Ca$_{x}$TiO$_3$",
"url": "https://arxiv.org/abs/2601.10516",
"version": "v1"
},
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