dorsal/arxiv
View SchemaPushing the hyperpolarizability to the limit
| Authors | Juefei Zhou, Mark G. Kuzyk, David S. Watkins |
|---|---|
| Categories | |
| ArXiv ID | physics/0605187 |
| URL | https://arxiv.org/abs/physics/0605187 |
| DOI | 10.1364/OL.31.002891 |
| Journal | Opt. Lett. 31, 2891-2893(2006) |
Abstract
We use numerical optimization to find a one-dimensional potential energy function that yields the largest hyperpolarizability, which we find is within 30% of the fundamental limit. Our results reveal insights into the character of the potential energy functions and wavefunctions that lead to the largest hyperpolarizability. We suggest that donor-acceptor molecules with a conjugated bridge with many sites of reduced conjugation to impart conjugation modulation may be the best paradigm for making materials with huge hyperpolarizabilities that approach the fundamental limit.
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"abstract": "We use numerical optimization to find a one-dimensional potential energy\nfunction that yields the largest hyperpolarizability, which we find is within\n30% of the fundamental limit. Our results reveal insights into the character of\nthe potential energy functions and wavefunctions that lead to the largest\nhyperpolarizability. We suggest that donor-acceptor molecules with a conjugated\nbridge with many sites of reduced conjugation to impart conjugation modulation\nmay be the best paradigm for making materials with huge hyperpolarizabilities\nthat approach the fundamental limit.",
"arxiv_id": "physics/0605187",
"authors": [
"Juefei Zhou",
"Mark G. Kuzyk",
"David S. Watkins"
],
"categories": [
"physics.optics",
"physics.chem-ph"
],
"doi": "10.1364/OL.31.002891",
"journal_ref": "Opt. Lett. 31, 2891-2893(2006)",
"title": "Pushing the hyperpolarizability to the limit",
"url": "https://arxiv.org/abs/physics/0605187"
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