dorsal/arxiv
View SchemaRotational structures of long-range diatomic molecules
| Authors | Bo Gao |
|---|---|
| Categories | |
| ArXiv ID | physics/0406090 |
| URL | https://arxiv.org/abs/physics/0406090 |
| DOI | 10.1140/epjd/e2004-00127-x |
Abstract
We present a systematic understanding of the rotational structure of a long-range (vibrationally highly-excited) diatomic molecule. For example, we show that depending on a quantum defect, the least-bound vibrational state of a diatomic molecule with $-C_n/r^n$ ($n>2$) asymptotic interaction can have only 1, 2, and up to a maximum of $n-2$ rotational states. A classification scheme of diatomic molecules is proposed, in which each class has a distinctive rotational structure and corresponds to different atom-atom scattering properties above the dissociation limit.
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"abstract": "We present a systematic understanding of the rotational structure of a\nlong-range (vibrationally highly-excited) diatomic molecule. For example, we\nshow that depending on a quantum defect, the least-bound vibrational state of a\ndiatomic molecule with $-C_n/r^n$ ($n\u003e2$) asymptotic interaction can have only\n1, 2, and up to a maximum of $n-2$ rotational states. A classification scheme\nof diatomic molecules is proposed, in which each class has a distinctive\nrotational structure and corresponds to different atom-atom scattering\nproperties above the dissociation limit.",
"arxiv_id": "physics/0406090",
"authors": [
"Bo Gao"
],
"categories": [
"physics.atom-ph",
"physics.chem-ph"
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"doi": "10.1140/epjd/e2004-00127-x",
"title": "Rotational structures of long-range diatomic molecules",
"url": "https://arxiv.org/abs/physics/0406090"
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