dorsal/arxiv
View SchemaOrtho-Para Conversion in CH3F. Self-Consistent Theoretical Model
| Authors | Pavel L. Chapovsky |
|---|---|
| Categories | |
| ArXiv ID | physics/0003046 |
| URL | https://arxiv.org/abs/physics/0003046 |
| Journal | Appl. Magn. Reson. v.18, 363-374 (2000) |
Abstract
A complete theoretical model of the nuclear spin conversion in 13CH3F induced by intramolecular ortho-para state mixing is proposed. The model contains parameters determined from the level-crossing spectra of the 13CH3F spin conversion. This set of parameters includes the ortho-para decoherence rate, the magnitude of the hyperfine spin-spin interaction between the molecular nuclei and the energy gap between the mixed ortho and para states. These parameters are found to be in a good agreement with their theoretical estimates.
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"abstract": "A complete theoretical model of the nuclear spin conversion in 13CH3F induced\nby intramolecular ortho-para state mixing is proposed. The model contains\nparameters determined from the level-crossing spectra of the 13CH3F spin\nconversion. This set of parameters includes the ortho-para decoherence rate,\nthe magnitude of the hyperfine spin-spin interaction between the molecular\nnuclei and the energy gap between the mixed ortho and para states. These\nparameters are found to be in a good agreement with their theoretical\nestimates.",
"arxiv_id": "physics/0003046",
"authors": [
"Pavel L. Chapovsky"
],
"categories": [
"physics.chem-ph"
],
"journal_ref": "Appl. Magn. Reson. v.18, 363-374 (2000)",
"title": "Ortho-Para Conversion in CH3F. Self-Consistent Theoretical Model",
"url": "https://arxiv.org/abs/physics/0003046"
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