dorsal/arxiv
View SchemaDynamics of Chemical Reactions: Open Equilibrium
| Authors | B. Zilbergleyt |
|---|---|
| Categories | |
| ArXiv ID | physics/0010013 |
| URL | https://arxiv.org/abs/physics/0010013 |
Abstract
Dynamic properties of chemical reactions and appropriate relationships for open chemical equilibrium are discussed in approach of the chemical dynamics. New way to calculate composition of chemical systems in open equilibrium, based on the amended equation for the change of Gibbs' free energy, was exemplified using reactions of cobalt double oxides with sulfur. Evaluated this way equilibrium reaction extents had a good match with values found by direct thermodynamic simulation. The developed method allows us to perform analysis of complex chemical systems without coefficients of thermodynamic activity. In cases when the coefficients are in need or just desirable, the method offers a simple way to calculate them. Possible systems to apply method of chemical dynamics are discussed.
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"abstract": "Dynamic properties of chemical reactions and appropriate relationships for\nopen chemical equilibrium are discussed in approach of the chemical dynamics.\nNew way to calculate composition of chemical systems in open equilibrium, based\non the amended equation for the change of Gibbs\u0027 free energy, was exemplified\nusing reactions of cobalt double oxides with sulfur. Evaluated this way\nequilibrium reaction extents had a good match with values found by direct\nthermodynamic simulation. The developed method allows us to perform analysis of\ncomplex chemical systems without coefficients of thermodynamic activity. In\ncases when the coefficients are in need or just desirable, the method offers a\nsimple way to calculate them. Possible systems to apply method of chemical\ndynamics are discussed.",
"arxiv_id": "physics/0010013",
"authors": [
"B. Zilbergleyt"
],
"categories": [
"physics.chem-ph"
],
"title": "Dynamics of Chemical Reactions: Open Equilibrium",
"url": "https://arxiv.org/abs/physics/0010013"
},
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