dorsal/arxiv
View SchemaIntegral equation for the interfacial tension of liquid metal in contact with ionic melt
| Authors | Oleg A. Kobelev, Alexandr V. Kobelev |
|---|---|
| Categories | |
| ArXiv ID | physics/0406103 |
| URL | https://arxiv.org/abs/physics/0406103 |
Abstract
The closed integral equations for the interfacial tension as a function of external polarization at the liquid metal - ionic melt interface are derived. The version of Popel'-Pavlov isotherm is applied to the analysis of electrocapillary curves (ecc), i.e. the dependences of interfacial tension on electrode potential. The interaction between adsorbed particles is taken into account within 'two exchange parameters' approximation. The type of the distribution of electric potential in the double electric layer (del) is assumed to be like 'in series connected capacitors'. The methods of solution are proposed for the analysis of the experimental ecc's.
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"date_created": "2026-03-02T18:00:50.375000Z",
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"abstract": "The closed integral equations for the interfacial tension as a function of\nexternal polarization at the liquid metal - ionic melt interface are derived.\nThe version of Popel\u0027-Pavlov isotherm is applied to the analysis of\nelectrocapillary curves (ecc), i.e. the dependences of interfacial tension on\nelectrode potential. The interaction between adsorbed particles is taken into\naccount within \u0027two exchange parameters\u0027 approximation. The type of the\ndistribution of electric potential in the double electric layer (del) is\nassumed to be like \u0027in series connected capacitors\u0027. The methods of solution\nare proposed for the analysis of the experimental ecc\u0027s.",
"arxiv_id": "physics/0406103",
"authors": [
"Oleg A. Kobelev",
"Alexandr V. Kobelev"
],
"categories": [
"physics.chem-ph"
],
"title": "Integral equation for the interfacial tension of liquid metal in contact with ionic melt",
"url": "https://arxiv.org/abs/physics/0406103"
},
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