dorsal/arxiv
View SchemaClassical-Wigner Phase Space Approximation to Cumulative Matrix Elements in Coherent Control
| Authors | B. R. McQuarrie, Dmitri G. Abrashkevich, Paul Brumer |
|---|---|
| Categories | |
| ArXiv ID | physics/0305132 |
| URL | https://arxiv.org/abs/physics/0305132 |
| DOI | 10.1063/1.1590962 |
| Journal | J. Chem. Phys. 119, 3606 (2003). |
Abstract
The classical limit of the Wigner-Weyl representation is used to approximate products of bound-continuum matrix elements that are fundamental to many coherent control computations. The range of utility of the method is quantified through an examination of model problems, single-channel Na_2 dissociation and multi-arrangement channel photodissociation of CH_2IBr. Very good agreement with the exact quantum results is found for a wide range of system parameters.
{
"annotation_id": "74428345-fd6b-4ae7-b74d-785e9ef37646",
"date_created": "2026-03-02T18:00:42.808000Z",
"date_modified": "2026-03-02T18:00:42.808000Z",
"file_hash": "e0c36e8a516fdda3a06391c2e98dd51ea72156cc4746bd9fe288d0cc9bafbdeb",
"private": false,
"record": {
"abstract": "The classical limit of the Wigner-Weyl representation is used to approximate\nproducts of bound-continuum matrix elements that are fundamental to many\ncoherent control computations. The range of utility of the method is quantified\nthrough an examination of model problems, single-channel Na_2 dissociation and\nmulti-arrangement channel photodissociation of CH_2IBr. Very good agreement\nwith the exact quantum results is found for a wide range of system parameters.",
"arxiv_id": "physics/0305132",
"authors": [
"B. R. McQuarrie",
"Dmitri G. Abrashkevich",
"Paul Brumer"
],
"categories": [
"physics.chem-ph",
"quant-ph"
],
"doi": "10.1063/1.1590962",
"journal_ref": "J. Chem. Phys. 119, 3606 (2003).",
"title": "Classical-Wigner Phase Space Approximation to Cumulative Matrix Elements in Coherent Control",
"url": "https://arxiv.org/abs/physics/0305132"
},
"schema_id": "dorsal/arxiv",
"source": {
"execution_id": "056c3c28-8ccc-4bb8-a5bf-116b229f999c",
"id": "arXiv Dataset IDs",
"type": "Model",
"variant": "snapshot-2026-03-01",
"version": "0.1.0"
},
"user_id": 1000002
}