dorsal/arxiv
View SchemaThe MCAS Way
| Authors | Joel M. Williams |
|---|---|
| Categories | |
| ArXiv ID | physics/9909053 |
| URL | https://arxiv.org/abs/physics/9909053 |
Abstract
The MCAS Way extends the MCAS concept of atomic orbitals to molecular bonding. There are many examples given for each bonding type. Part I: The MCAS atomic orbital concept. There are no spherical orbitals and spin pairing does not occur through spin reversal. Quantum numbers do not validate coexistence in identical space. Part II: Single bonds. There are no sigma-bonds wherein two electrons occupy identical space on a line between nuclei; only off-axis (Xi) bonding. Covalent bonding is purely electrostatic; just like ionic bonding. Part III: Triple bonds. There are no Pi-bonds in a triple bond. Part IV: Simple double bonds. There are no sigma bonds; only Pi| and Pi_ bonds. Part V: Multiple bonds. The traditional Pi-cloud is only a group of reciprocating, vertically pumping, electron pistons. Electrons conjugate by flowing around nuclei in the nuclear plane. Atoms adopt a twelve-lobed (T12) orbital arrangement for multiple bonding. Aromaticity is defined by 2(2n+1), not (4n+2). Part VI: Miscellaneous compounds. Isoelectronic XO3, phosphorous and its oxides, and boranes.
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"abstract": "The MCAS Way extends the MCAS concept of atomic orbitals to molecular\nbonding. There are many examples given for each bonding type. Part I: The MCAS\natomic orbital concept. There are no spherical orbitals and spin pairing does\nnot occur through spin reversal. Quantum numbers do not validate coexistence in\nidentical space. Part II: Single bonds. There are no sigma-bonds wherein two\nelectrons occupy identical space on a line between nuclei; only off-axis (Xi)\nbonding. Covalent bonding is purely electrostatic; just like ionic bonding.\nPart III: Triple bonds. There are no Pi-bonds in a triple bond. Part IV: Simple\ndouble bonds. There are no sigma bonds; only Pi| and Pi_ bonds. Part V:\nMultiple bonds. The traditional Pi-cloud is only a group of reciprocating,\nvertically pumping, electron pistons. Electrons conjugate by flowing around\nnuclei in the nuclear plane. Atoms adopt a twelve-lobed (T12) orbital\narrangement for multiple bonding. Aromaticity is defined by 2(2n+1), not\n(4n+2). Part VI: Miscellaneous compounds. Isoelectronic XO3, phosphorous and\nits oxides, and boranes.",
"arxiv_id": "physics/9909053",
"authors": [
"Joel M. Williams"
],
"categories": [
"physics.gen-ph"
],
"title": "The MCAS Way",
"url": "https://arxiv.org/abs/physics/9909053"
},
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