dorsal/arxiv
View SchemaAn Analytical Formulation of CPMAS
| Authors | F. Marica, R. F. Snider |
|---|---|
| Categories | |
| ArXiv ID | physics/0203003 |
| URL | https://arxiv.org/abs/physics/0203003 |
Abstract
An exact expression for the cross polarization between two spin-1/2 particles is derived from the quantum Liouville equation. This is given in the form of two integrodifferential equations. These can be solved exactly in the static case (no sample spinning) and a powder average performed numerically. With magic angle spinning, the neglect of certain interference terms simplifies the numerical calculation. A further assumption decoupling the calculation of the sidebands gives a very simple formula that is capable of giving a qualitative interpretation of all experimental observations. Examples are given illustrating typical buildup curves and CPMAS matching profiles.
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"abstract": "An exact expression for the cross polarization between two spin-1/2 particles\nis derived from the quantum Liouville equation. This is given in the form of\ntwo integrodifferential equations. These can be solved exactly in the static\ncase (no sample spinning) and a powder average performed numerically. With\nmagic angle spinning, the neglect of certain interference terms simplifies the\nnumerical calculation. A further assumption decoupling the calculation of the\nsidebands gives a very simple formula that is capable of giving a qualitative\ninterpretation of all experimental observations. Examples are given\nillustrating typical buildup curves and CPMAS matching profiles.",
"arxiv_id": "physics/0203003",
"authors": [
"F. Marica",
"R. F. Snider"
],
"categories": [
"physics.chem-ph"
],
"title": "An Analytical Formulation of CPMAS",
"url": "https://arxiv.org/abs/physics/0203003"
},
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