dorsal/arxiv
View SchemaStatic polarizability of molecular materials: environmental and vibrational contributions
| Authors | Francesca Terenziani, Anna Painelli, Zoltan G. Soos |
|---|---|
| Categories | |
| ArXiv ID | physics/0307111 |
| URL | https://arxiv.org/abs/physics/0307111 |
Abstract
Modeling the dielectric behavior of molecular materials made up of large pi-conjugated molecules is an interesting and complex task. Here we address linear polarizabilities, and the related dielectric constant, of molecular crystals and aggregates made up of closed-shell pi-conjugated molecules with either a non-polar or largely polar ground-state, and also examine the behavior of mixed-valence (or charge-transfer) organic salts. We recognize important collective phenomena due to supramolecular interactions in materials with large molecular polarizabilities, and underline large vibrational contributions to the polarizability in materials with largely delocalized electrons.
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"date_created": "2026-03-02T18:00:46.913000Z",
"date_modified": "2026-03-02T18:00:46.913000Z",
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"abstract": "Modeling the dielectric behavior of molecular materials made up of large\npi-conjugated molecules is an interesting and complex task. Here we address\nlinear polarizabilities, and the related dielectric constant, of molecular\ncrystals and aggregates made up of closed-shell pi-conjugated molecules with\neither a non-polar or largely polar ground-state, and also examine the behavior\nof mixed-valence (or charge-transfer) organic salts. We recognize important\ncollective phenomena due to supramolecular interactions in materials with large\nmolecular polarizabilities, and underline large vibrational contributions to\nthe polarizability in materials with largely delocalized electrons.",
"arxiv_id": "physics/0307111",
"authors": [
"Francesca Terenziani",
"Anna Painelli",
"Zoltan G. Soos"
],
"categories": [
"physics.chem-ph",
"cond-mat"
],
"title": "Static polarizability of molecular materials: environmental and vibrational contributions",
"url": "https://arxiv.org/abs/physics/0307111"
},
"schema_id": "dorsal/arxiv",
"source": {
"execution_id": "df7551fd-e014-4781-9448-bd1ba978379a",
"id": "arXiv Dataset IDs",
"type": "Model",
"variant": "snapshot-2026-03-01",
"version": "0.1.0"
},
"user_id": 1000002
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