dorsal/arxiv
View SchemaElectron diffraction data on structural transformations in free clucters of argon
| Authors | Spartak I. Kovalenko, Oleksandr G. Danylchenko, Vladimir N. Samovarov |
|---|---|
| Categories | |
| ArXiv ID | physics/0402063 |
| URL | https://arxiv.org/abs/physics/0402063 |
Abstract
An electron diffraction technique is used to study the structure of clusters formed in an isentropically expanding supersonic argon jet. The formation of the hcp phase with increasing cluster size is reliably detected for the first time. Observations are made for mean cluster sizes N in the range from 1x10^3 to 8x10^4 atoms/cluster. An analysis of the shape of the diffraction peaks is carried out. It is found that in the range N <= 2x10^3 atoms/cluster, where the clusters are icosahedral, the profiles of the diffraction peaks are well approximated by a Lorentzian. For fcc clusters with N >= 3x10^3 atoms/cluster a better approximation is the standard Gaussian function. In the case N >= 1x10^4 atoms/cluster one observes peaks of the hcp phase in addition to the fcc peaks. The intensity of the hcp peaks increases with increasing cluster size, and for N = 8x10^4 atoms/cluster, the (110), (101), (103), and (202) peaks, characteristic only for the hcp phase, are clearly registered in addition to the fcc peaks. A possible mechanism for the formation of the hcp structure in Ar clusters is proposed.
{
"annotation_id": "5a19b749-7bde-40ac-b769-dc32c98d152d",
"date_created": "2026-03-02T18:00:50.423000Z",
"date_modified": "2026-03-02T18:00:50.423000Z",
"file_hash": "ef6338138804f902f42e1810402cbe76def224e333f6a6deaea8e31be2e7f9dd",
"private": false,
"record": {
"abstract": "An electron diffraction technique is used to study the structure of clusters\nformed in an isentropically expanding supersonic argon jet. The formation of\nthe hcp phase with increasing cluster size is reliably detected for the first\ntime. Observations are made for mean cluster sizes N in the range from 1x10^3\nto 8x10^4 atoms/cluster. An analysis of the shape of the diffraction peaks is\ncarried out. It is found that in the range N \u003c= 2x10^3 atoms/cluster, where the\nclusters are icosahedral, the profiles of the diffraction peaks are well\napproximated by a Lorentzian. For fcc clusters with N \u003e= 3x10^3 atoms/cluster a\nbetter approximation is the standard Gaussian function. In the case N \u003e= 1x10^4\natoms/cluster one observes peaks of the hcp phase in addition to the fcc peaks.\nThe intensity of the hcp peaks increases with increasing cluster size, and for\nN = 8x10^4 atoms/cluster, the (110), (101), (103), and (202) peaks,\ncharacteristic only for the hcp phase, are clearly registered in addition to\nthe fcc peaks. A possible mechanism for the formation of the hcp structure in\nAr clusters is proposed.",
"arxiv_id": "physics/0402063",
"authors": [
"Spartak I. Kovalenko",
"Oleksandr G. Danylchenko",
"Vladimir N. Samovarov"
],
"categories": [
"physics.atm-clus"
],
"title": "Electron diffraction data on structural transformations in free clucters of argon",
"url": "https://arxiv.org/abs/physics/0402063"
},
"schema_id": "dorsal/arxiv",
"source": {
"execution_id": "fe34502c-8126-415d-9988-222919dae0de",
"id": "arXiv Dataset IDs",
"type": "Model",
"variant": "snapshot-2026-03-01",
"version": "0.1.0"
},
"user_id": 1000002
}