dorsal/arxiv
View SchemaVibrational Frequencies of the 2p^2A^"_2 and 3d^2E^" States of the Triatomic Deuterium Molecule
| Authors | U. Mueller, M. Braun, R. Reichle, R. F. Salzgeber |
|---|---|
| Categories | |
| ArXiv ID | physics/9712040 |
| URL | https://arxiv.org/abs/physics/9712040 |
| DOI | 10.1063/1.475859 |
Abstract
We investigated the vibrational energies in the 2p^2A^"_2 and 3d^2E^" states of the triatomic deuterium molecule D_3. The experiments were performed using a fast neutral beam photoionization spectrometer recently developed at Freiburg. A depletion type optical double-resonance scheme using two pulsed dye lasers was applied. The measured vibrational frequencies of the 2p^2A^"_2 state of D_3 are compared to those of H_3 and to theoretical values calculated from an ab initio potential energy surface. The data give insight into the importance of the coupling between the valence electron and the ion core.
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"abstract": "We investigated the vibrational energies in the 2p^2A^\"_2 and 3d^2E^\" states\nof the triatomic deuterium molecule D_3. The experiments were performed using a\nfast neutral beam photoionization spectrometer recently developed at Freiburg.\nA depletion type optical double-resonance scheme using two pulsed dye lasers\nwas applied. The measured vibrational frequencies of the 2p^2A^\"_2 state of D_3\nare compared to those of H_3 and to theoretical values calculated from an ab\ninitio potential energy surface. The data give insight into the importance of\nthe coupling between the valence electron and the ion core.",
"arxiv_id": "physics/9712040",
"authors": [
"U. Mueller",
"M. Braun",
"R. Reichle",
"R. F. Salzgeber"
],
"categories": [
"physics.chem-ph"
],
"doi": "10.1063/1.475859",
"title": "Vibrational Frequencies of the 2p^2A^\"_2 and 3d^2E^\" States of the Triatomic Deuterium Molecule",
"url": "https://arxiv.org/abs/physics/9712040"
},
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