dorsal/arxiv
View SchemaLaser-Induced Vibrational Frequency Shift
| Authors | D. L. Andrews R. G. Crisp |
|---|---|
| Categories | |
| ArXiv ID | physics/0502136 |
| URL | https://arxiv.org/abs/physics/0502136 |
Abstract
A mechanism is explored whereby intense laser radiation induces an optical force between the constituent atoms of a molecule. In the case of a diatomic molecule the effect results in a modification of the vibrational potential, and using perturbation theory it is shown that this reduces the stretching frequency. Model calculations on selected diatomics indicate that the extent of the frequency shift should, under suitable conditions, be detectable by Raman spectroscopy.
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"abstract": "A mechanism is explored whereby intense laser radiation induces an optical\nforce between the constituent atoms of a molecule. In the case of a diatomic\nmolecule the effect results in a modification of the vibrational potential, and\nusing perturbation theory it is shown that this reduces the stretching\nfrequency. Model calculations on selected diatomics indicate that the extent of\nthe frequency shift should, under suitable conditions, be detectable by Raman\nspectroscopy.",
"arxiv_id": "physics/0502136",
"authors": [
"D. L. Andrews R. G. Crisp"
],
"categories": [
"physics.optics",
"physics.chem-ph"
],
"title": "Laser-Induced Vibrational Frequency Shift",
"url": "https://arxiv.org/abs/physics/0502136"
},
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