dorsal/arxiv
View SchemaLaser Spectroscopic Measurement of Helium Isotope Ratios
| Authors | L. -B. Wang, P. Mueller, R. J. Holt, Z. -T. Lu, T. P. O'Connor, Y. Sano, N. C. Sturchio |
|---|---|
| Categories | |
| ArXiv ID | physics/0311121 |
| URL | https://arxiv.org/abs/physics/0311121 |
| DOI | 10.1029/2003GL017242 |
| Journal | Geophysical Research Letters 30, 1592 (2003) |
Abstract
A sensitive laser spectroscopic method has been applied to the quantitative determination of the isotope ratio of helium at the level of 3He/4He = 10^-7 - 10^-5. The resonant absorption of 1083 nm laser light by the metastable 3He atoms in a discharge cell was measured with the frequency modulation saturation spectroscopy technique while the abundance of 4He was measured by a direct absorption technique. The results on three different samples extracted from the atmosphere and commercial helium gas were in good agreement with values obtained with mass spectrometry. The achieved 3-sigma detection limit of 3He in helium is 4 x 10^-9. This demonstration required a 200 micro-L STP sample of He. The sensitivity can be further improved, and the required sample size reduced, by several orders of magnitude with the addition of cavity enhanced spectroscopy.
{
"annotation_id": "476cca40-6e81-4b5e-90e5-68317dd1c335",
"date_created": "2026-03-02T18:00:46.302000Z",
"date_modified": "2026-03-02T18:00:46.302000Z",
"file_hash": "ddfc960231dd25c154ef642b356a141b3a6c9838bdfbe719f1596681265ff99d",
"private": false,
"record": {
"abstract": "A sensitive laser spectroscopic method has been applied to the quantitative\ndetermination of the isotope ratio of helium at the level of 3He/4He = 10^-7 -\n10^-5. The resonant absorption of 1083 nm laser light by the metastable 3He\natoms in a discharge cell was measured with the frequency modulation saturation\nspectroscopy technique while the abundance of 4He was measured by a direct\nabsorption technique. The results on three different samples extracted from the\natmosphere and commercial helium gas were in good agreement with values\nobtained with mass spectrometry. The achieved 3-sigma detection limit of 3He in\nhelium is 4 x 10^-9. This demonstration required a 200 micro-L STP sample of\nHe. The sensitivity can be further improved, and the required sample size\nreduced, by several orders of magnitude with the addition of cavity enhanced\nspectroscopy.",
"arxiv_id": "physics/0311121",
"authors": [
"L. -B. Wang",
"P. Mueller",
"R. J. Holt",
"Z. -T. Lu",
"T. P. O\u0027Connor",
"Y. Sano",
"N. C. Sturchio"
],
"categories": [
"physics.atom-ph",
"physics.geo-ph"
],
"doi": "10.1029/2003GL017242",
"journal_ref": "Geophysical Research Letters 30, 1592 (2003)",
"title": "Laser Spectroscopic Measurement of Helium Isotope Ratios",
"url": "https://arxiv.org/abs/physics/0311121"
},
"schema_id": "dorsal/arxiv",
"source": {
"execution_id": "f2b4161c-241c-49c8-b36e-0bcf51519743",
"id": "arXiv Dataset IDs",
"type": "Model",
"variant": "snapshot-2026-03-01",
"version": "0.1.0"
},
"user_id": 1000002
}