dorsal/arxiv
View SchemaMolecular collisions in ultracold atomic gases
| Authors | Jeremy M. Hutson, Pavel Soldan |
|---|---|
| Categories | |
| ArXiv ID | physics/0610219 |
| URL | https://arxiv.org/abs/physics/0610219 |
| DOI | 10.1080/01442350601084562 |
| Journal | Int. Rev. Phys. Chem. 26, 1-28 (2007) |
Abstract
It has recently become possible to form molecules in ultracold gases of trapped alkali metal atoms. Once formed, the molecules may undergo elastic, inelastic and reactive collisions. Inelastic and reactive collisions are particularly important because they release kinetic energy and eject atoms and molecules from the trap. The theory needed to handle such collisions is presented and recent quantum dynamics calculations on ultracold atom-diatom collisions of spin-polarised Li + Li_2, Na + Na_2 and K + K_2 are described. All these systems have potential energy surfaces on which barrierless atom exchange reactions can occur, and both inelastic and reactive rates are very fast (typically k(inel) > 10^{-10} cm^3 s^-1 in the Wigner regime).
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"abstract": "It has recently become possible to form molecules in ultracold gases of\ntrapped alkali metal atoms. Once formed, the molecules may undergo elastic,\ninelastic and reactive collisions. Inelastic and reactive collisions are\nparticularly important because they release kinetic energy and eject atoms and\nmolecules from the trap. The theory needed to handle such collisions is\npresented and recent quantum dynamics calculations on ultracold atom-diatom\ncollisions of spin-polarised Li + Li_2, Na + Na_2 and K + K_2 are described.\nAll these systems have potential energy surfaces on which barrierless atom\nexchange reactions can occur, and both inelastic and reactive rates are very\nfast (typically k(inel) \u003e 10^{-10} cm^3 s^-1 in the Wigner regime).",
"arxiv_id": "physics/0610219",
"authors": [
"Jeremy M. Hutson",
"Pavel Soldan"
],
"categories": [
"physics.atom-ph",
"physics.chem-ph"
],
"doi": "10.1080/01442350601084562",
"journal_ref": "Int. Rev. Phys. Chem. 26, 1-28 (2007)",
"title": "Molecular collisions in ultracold atomic gases",
"url": "https://arxiv.org/abs/physics/0610219"
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