{
  "annotation_id": "28873e9c-19df-4821-802d-19689b141d66",
  "date_created": "2026-03-02T18:00:57.341000Z",
  "date_modified": "2026-03-02T18:00:57.341000Z",
  "file_hash": "f0595412136067859b6c116f282151bd6bde180319c26f1ad21f09df9922aa3f",
  "private": false,
  "record": {
    "abstract": "Everything that is not prohibited is permissible. So, what is prohibited in\nthe course of chemical reactions, heat transfer and other dissipative\nprocesses? Is it possible to \"overshoot\" the equilibrium, and if yes, then how\nfar? Thermodynamically allowed and prohibited trajectories of processes are\ndiscussed by the example of effects of equilibrium encircling. The complete\ntheory of thermodynamically accessible states is presented. The space of all\nthermodynamically admissible paths is presented by projection on the\n\"thermodynamic tree\", that is the tree of the related thermodynamic potential\n(entropy, free energy, free enthalpy) in the balance polyhedron. The stationary\nstates and limit points for open systems are localized too.",
    "arxiv_id": "physics/0505135",
    "authors": [
      "A. N. Gorban",
      "G. S. Yablonsky"
    ],
    "categories": [
      "physics.chem-ph",
      "physics.gen-ph"
    ],
    "title": "Thermodynamic theory of kinetic overshoots",
    "url": "https://arxiv.org/abs/physics/0505135"
  },
  "schema_id": "dorsal/arxiv",
  "source": {
    "execution_id": "504b948f-1dd2-4360-aae9-e7e82508b472",
    "id": "arXiv Dataset IDs",
    "type": "Model",
    "variant": "snapshot-2026-03-01",
    "version": "0.1.0"
  },
  "user_id": 1000002
}