dorsal/arxiv
View SchemaTemperature dependence of optical rotation study on parity-violating phase transition of D-, L-, and DL-alanine
| Authors | Fan Bai, Miao Zhang, Wenqing Wang |
|---|---|
| Categories | |
| ArXiv ID | physics/0210109 |
| URL | https://arxiv.org/abs/physics/0210109 |
Abstract
Chiral molecules are characterized by a specific optical rotation angle. An experimental method was presented to dissect the temperature dependence of the optical rotation angle with the molecular chirality of D-alanine, L-alanine and DL-alanine crystals. Salam hypothesis predicted that quantum mechanical cooperative and condensation phenomena may give rise to a second order phase transition below a critical temperature linking the transformation of D-amino acids to L-amino acids due to parity-violating energy difference. The temperature- dependent measurement of the optical rotation angle of D-, L- and DL-alanine crystals provided the direct evidence of the phase transition, but denied the configuration change from D-alanine to L-alanine. New views on Salam hypothesis are presented to demonstrate its importance in the application of low temperature enantiomeric separation and the origin of biochirality.
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"abstract": "Chiral molecules are characterized by a specific optical rotation angle. An\nexperimental method was presented to dissect the temperature dependence of the\noptical rotation angle with the molecular chirality of D-alanine, L-alanine and\nDL-alanine crystals. Salam hypothesis predicted that quantum mechanical\ncooperative and condensation phenomena may give rise to a second order phase\ntransition below a critical temperature linking the transformation of D-amino\nacids to L-amino acids due to parity-violating energy difference. The\ntemperature- dependent measurement of the optical rotation angle of D-, L- and\nDL-alanine crystals provided the direct evidence of the phase transition, but\ndenied the configuration change from D-alanine to L-alanine. New views on Salam\nhypothesis are presented to demonstrate its importance in the application of\nlow temperature enantiomeric separation and the origin of biochirality.",
"arxiv_id": "physics/0210109",
"authors": [
"Fan Bai",
"Miao Zhang",
"Wenqing Wang"
],
"categories": [
"physics.bio-ph"
],
"title": "Temperature dependence of optical rotation study on parity-violating phase transition of D-, L-, and DL-alanine",
"url": "https://arxiv.org/abs/physics/0210109"
},
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