{
  "annotation_id": "04439d66-8579-4754-92f5-38e3027557c2",
  "date_created": "2026-03-02T18:00:32.238000Z",
  "date_modified": "2026-03-02T18:00:32.238000Z",
  "file_hash": "fd6038b345e42cf995cf3f44483a247e016a1c352b8ef46b79c566bd6386da48",
  "private": false,
  "record": {
    "abstract": "Earlier it has been supposed that the law of conservation of energy in\nchemical reactions has the following form: DU=DQ-PDV+SUM(muiDN) In the present\npaper it has been proved by means of the theory of ordinary differential\nequations that in the biggest part of the chemical reactions it must have the\nfollowing form: DU=DQ+PDV+SUM(muiDN) The result obtained allows to explain a\nparadox in chemical thermodynamics: the heat of chemical processes measured by\ncalorimetry and by the Vant-Hoff equation differs very much from each other.\nThe result is confirmed by many experiments.",
    "arxiv_id": "physics/0010052",
    "authors": [
      "I. A. Stepanov"
    ],
    "categories": [
      "physics.chem-ph"
    ],
    "title": "The Law of Conservation of Energy in Chemical Reactions",
    "url": "https://arxiv.org/abs/physics/0010052"
  },
  "schema_id": "dorsal/arxiv",
  "source": {
    "execution_id": "dd691b7c-9704-4ba1-bbc7-2dcd9fc48468",
    "id": "arXiv Dataset IDs",
    "type": "Model",
    "variant": "snapshot-2026-03-01",
    "version": "0.1.0"
  },
  "user_id": 1000002
}