dorsal/arxiv
View SchemaThe Law of Conservation of Energy in Chemical Reactions
| Authors | I. A. Stepanov |
|---|---|
| Categories | |
| ArXiv ID | physics/0010052 |
| URL | https://arxiv.org/abs/physics/0010052 |
Abstract
Earlier it has been supposed that the law of conservation of energy in chemical reactions has the following form: DU=DQ-PDV+SUM(muiDN) In the present paper it has been proved by means of the theory of ordinary differential equations that in the biggest part of the chemical reactions it must have the following form: DU=DQ+PDV+SUM(muiDN) The result obtained allows to explain a paradox in chemical thermodynamics: the heat of chemical processes measured by calorimetry and by the Vant-Hoff equation differs very much from each other. The result is confirmed by many experiments.
{
"annotation_id": "04439d66-8579-4754-92f5-38e3027557c2",
"date_created": "2026-03-02T18:00:32.238000Z",
"date_modified": "2026-03-02T18:00:32.238000Z",
"file_hash": "fd6038b345e42cf995cf3f44483a247e016a1c352b8ef46b79c566bd6386da48",
"private": false,
"record": {
"abstract": "Earlier it has been supposed that the law of conservation of energy in\nchemical reactions has the following form: DU=DQ-PDV+SUM(muiDN) In the present\npaper it has been proved by means of the theory of ordinary differential\nequations that in the biggest part of the chemical reactions it must have the\nfollowing form: DU=DQ+PDV+SUM(muiDN) The result obtained allows to explain a\nparadox in chemical thermodynamics: the heat of chemical processes measured by\ncalorimetry and by the Vant-Hoff equation differs very much from each other.\nThe result is confirmed by many experiments.",
"arxiv_id": "physics/0010052",
"authors": [
"I. A. Stepanov"
],
"categories": [
"physics.chem-ph"
],
"title": "The Law of Conservation of Energy in Chemical Reactions",
"url": "https://arxiv.org/abs/physics/0010052"
},
"schema_id": "dorsal/arxiv",
"source": {
"execution_id": "dd691b7c-9704-4ba1-bbc7-2dcd9fc48468",
"id": "arXiv Dataset IDs",
"type": "Model",
"variant": "snapshot-2026-03-01",
"version": "0.1.0"
},
"user_id": 1000002
}